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Please use this identifier to cite or link to this item: http://dspace.bits-pilani.ac.in:8080/jspui/handle/123456789/18552
Title: Thermodynamic Study of the Vaporization of Cerium Orthophosphate
Authors: Guido, M
Balducci, G
De Maria, G
Gigli, G
Keywords: Chemistry
Thermodynamic
Journal of the Chemical Society : Faraday Transaction - I
Issue Date: 1977
Publisher: Journal of the Chemical Society : Faraday Transaction - I. The Chemical Society, London. 1977, 73 (1)
Abstract: The high temperature Knudsen cell mass spectrometric technique has been used to study the vaporization behaviour of solid cerium orthophosphate over the temperature range 1700–1850 K. From the second- and third-law analyses of the equilibrium reaction: CePO4(s)= CeO2(g)+ PO2(g), the following standard heat of formation of CePO4(s) has been derived: ΔH°298,f[CePO4(s)]=–1898.5 ± 31.5 kJ mol–1. These results are discussed and compared with those obtained by other authors for other LnPO4 compounds.
URI: http://dspace.bits-pilani.ac.in:8080/jspui/handle/123456789/18552
Appears in Collections:Journal Articles (before-1995)

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