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Title: | Reversible Temperature Dependent Spectral Shift in the Infrared Spectrum of DNA (Na) in the Dry Solid State |
Authors: | Rossiter, V. |
Keywords: | Chemistry Reversible Temperature DNA Dry Solid State Journal of the Chemical Society : Faraday Transaction - I |
Issue Date: | 1977 |
Publisher: | Journal of the Chemical Society : Faraday Transaction - I. The Chemical Society, London. 1977, 73 (2) |
Abstract: | The unpolariscd infrared spectrum of freeze-dried layers of calf thymus DNA(Na) has been recorded over the range from 4000 cm-1 to 625 cm-1 at temperatures between — 45CC and + 95CC. Throughout the temperature variations, the samples were maintained in a very dry state. The position of the absorption band at approximately 1230 cm-1 is shown to depend on temperature and to be capable of a reversible shift over a range of ~16 cm-1. The results arc compared with previously published low-frequency dielectric measurements on similar samples and with polarised infrared measurements showing the influence of changes in relative humidity on the structure of DNA salts. |
URI: | http://dspace.bits-pilani.ac.in:8080/jspui/handle/123456789/18608 |
Appears in Collections: | Journal Articles (before-1995) |
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0263-0266.pdf Restricted Access | 251.05 kB | Adobe PDF | View/Open Request a copy |
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