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Please use this identifier to cite or link to this item: http://dspace.bits-pilani.ac.in:8080/jspui/handle/123456789/18625
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dc.contributor.authorCundall, Robert B.-
dc.contributor.authorFussey, David E.-
dc.contributor.authorHarrison, Andrew J.-
dc.contributor.authorLampard, Desmond-
dc.date.accessioned2025-04-11T05:02:35Z-
dc.date.available2025-04-11T05:02:35Z-
dc.date.issued1978-
dc.identifier.urihttp://dspace.bits-pilani.ac.in:8080/jspui/handle/123456789/18625-
dc.description.abstractShock heating of acetylene and ethylene, under the conditions 1500–2500 K, 1–2 bar and molar fraction 0.07–2 % hydrocarbon in argon, has produced spectrographic evidence concerning the products of pyrolysis. Kinetic spectrophotometry was used in the wavelength range 250 nm-1.5 µm. The variation of the absorption spectra with temperature, hydrocarbon pressure and time were investigated, and suggest that polyacetylenes were formed. Simple kinetic analysis has given rate constants for the formation of polyacetylenes and the polyacetylene concentration was found to reach an equilibrium value within the observation time in some cases.en_US
dc.language.isoenen_US
dc.publisherJournal of the Chemical Society : Faraday Transaction - I. The Chemical Society, London. 1978, 74 (06)en_US
dc.subjectChemistryen_US
dc.subjectShock tube studiesen_US
dc.subjectHigh-temperature pyrolysisen_US
dc.subjectJournal of the Chemical Society : Faraday Transaction - Ien_US
dc.titleShock tube studies of the high temperature pyrolysis of acetylene and ethyleneen_US
dc.typeArticleen_US
Appears in Collections:Journal Articles (before-1995)

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