Please use this identifier to cite or link to this item:
http://dspace.bits-pilani.ac.in:8080/jspui/handle/123456789/18625| Title: | Shock tube studies of the high temperature pyrolysis of acetylene and ethylene |
| Authors: | Cundall, Robert B. Fussey, David E. Harrison, Andrew J. Lampard, Desmond |
| Keywords: | Chemistry Shock tube studies High-temperature pyrolysis Journal of the Chemical Society : Faraday Transaction - I |
| Issue Date: | 1978 |
| Publisher: | Journal of the Chemical Society : Faraday Transaction - I. The Chemical Society, London. 1978, 74 (06) |
| Abstract: | Shock heating of acetylene and ethylene, under the conditions 1500–2500 K, 1–2 bar and molar fraction 0.07–2 % hydrocarbon in argon, has produced spectrographic evidence concerning the products of pyrolysis. Kinetic spectrophotometry was used in the wavelength range 250 nm-1.5 µm. The variation of the absorption spectra with temperature, hydrocarbon pressure and time were investigated, and suggest that polyacetylenes were formed. Simple kinetic analysis has given rate constants for the formation of polyacetylenes and the polyacetylene concentration was found to reach an equilibrium value within the observation time in some cases. |
| URI: | http://dspace.bits-pilani.ac.in:8080/jspui/handle/123456789/18625 |
| Appears in Collections: | Journal Articles (before-1995) |
Files in This Item:
| File | Description | Size | Format | |
|---|---|---|---|---|
| 1403-1409.pdf Restricted Access | 409.29 kB | Adobe PDF | View/Open Request a copy |
Items in DSpace are protected by copyright, with all rights reserved, unless otherwise indicated.