Please use this identifier to cite or link to this item:
http://dspace.bits-pilani.ac.in:8080/jspui/handle/123456789/18762| Title: | Resonance Raman spectra of carbonium ions adsorbed on porous Vycor glass |
| Authors: | Yamamoto, Yoichiro Yamada, Haruka |
| Keywords: | Chemistry Carbonium ions Resonance Raman spectroscopy Journal of the Chemical Society : Faraday Transaction - I |
| Issue Date: | 1978 |
| Publisher: | Journal of the Chemical Society : Faraday Transaction - I. The Chemical Society, London. 1978, 74 (06) |
| Abstract: | Measurements of Raman spectra for unstable intermediates adsorbed on porous Vycor glass (PVG) have been made. When 1,1-diphenylethylene (DPE) was adsorbed on PVG, some unstable intermediates, blue, green and yellow species, were produced. Resonance Raman spectra of the green and yellow samples were obtained. The green species showed three new bands at 2975, 2930 and 2873 cm–1 and the yellow species one at 2930 cm–1. The observed Raman spectra confirm the existence of two kinds of carbonium ions. The structure of the carbonium ions and the formation mechanism of the intermediates were considered. Applicability of this technique to the study of small quantities of surface species is discussed. |
| URI: | http://dspace.bits-pilani.ac.in:8080/jspui/handle/123456789/18762 |
| Appears in Collections: | Journal Articles (before-1995) |
Files in This Item:
| File | Description | Size | Format | |
|---|---|---|---|---|
| 1562-1568.pdf Restricted Access | 337.1 kB | Adobe PDF | View/Open Request a copy |
Items in DSpace are protected by copyright, with all rights reserved, unless otherwise indicated.