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Title: | Catalyst participation in the reduction of sulphur dioxide by carbon monoxide in the presence of water and oxygen |
Authors: | Hibbert, D. Brynn Tseung, Alfred C. C. |
Keywords: | Chemistry Sulfur dioxide Carbon monoxide Journal of the Chemical Society : Faraday Transaction - I |
Issue Date: | 1978 |
Publisher: | Journal of the Chemical Society : Faraday Transaction - I. The Chemical Society, London. 1978, 74 (08) |
Abstract: | Copper supported on alumina is a catalyst for the reduction of sulphur dioxide by carbon monoxide. In the presence of water and oxygen, calculation of the equilibrium state of the gas phase and condensed phase by a free energy minimisation method reveals that for certain combinations of gas composition and temperature, copper(II) sulphide will be formed. Copper was converted to copper sulphide when used as a catalyst for the reduction of a stoichiometric mixture of sulphur dioxide and carbon monoxide containing 2.4 % water at 580°C. Oxygen is a poison for the reaction. |
URI: | http://dspace.bits-pilani.ac.in:8080/jspui/handle/123456789/18824 |
Appears in Collections: | Journal Articles (before-1995) |
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1981-1989.pdf Restricted Access | 400.9 kB | Adobe PDF | View/Open Request a copy |
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