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http://dspace.bits-pilani.ac.in:8080/jspui/handle/123456789/18861| Title: | On the Hydrolysis of Agn, T1H, Sn111 and CuI[1 |
| Authors: | Asmus, Klaus-Dieter Toffel, Peter Bonifacio, Marija |
| Keywords: | Chemistry Hydrolysis Journal of the Chemical Society : Faraday Transaction - I |
| Issue Date: | 1978 |
| Publisher: | Journal of the Chemical Society : Faraday Transaction - I. The Chemical Society, London. 1978, 74 (08) |
| Abstract: | Using pulse radiolysis with optical, conductometric and polarographic detection it is shown that the oxidation of T1+, Ag+, Cu2 ! and Sn2 ■ by hydroxyl radicals proceeds via on OH adduct: Mc"+ + •OH Me(OH)'l+. Depending on pH, the OH adduct may react with a proton followed by water elimination, may add OH- or react with water followed by elimination of a proton. The pA" values for the equilibria Me('l+‘)+ = Mc(OH)n+ ~ Me(OH)O-1)4 decrease with increasing state of oxidation of Me. The oxidative properties decrease with increasing state of hydrolysis. |
| URI: | http://dspace.bits-pilani.ac.in:8080/jspui/handle/123456789/18861 |
| Appears in Collections: | Journal Articles (before-1995) |
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| File | Description | Size | Format | |
|---|---|---|---|---|
| 1820-1826-x.pdf Restricted Access | 449.17 kB | Adobe PDF | View/Open Request a copy |
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