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DC Field | Value | Language |
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dc.contributor.author | Asmus, Klaus-Dieter | - |
dc.contributor.author | Toffel, Peter | - |
dc.contributor.author | Bonifacio, Marija | - |
dc.date.accessioned | 2025-05-06T11:09:34Z | - |
dc.date.available | 2025-05-06T11:09:34Z | - |
dc.date.issued | 1978 | - |
dc.identifier.uri | http://dspace.bits-pilani.ac.in:8080/jspui/handle/123456789/18861 | - |
dc.description.abstract | Using pulse radiolysis with optical, conductometric and polarographic detection it is shown that the oxidation of T1+, Ag+, Cu2 ! and Sn2 ■ by hydroxyl radicals proceeds via on OH adduct: Mc"+ + •OH Me(OH)'l+. Depending on pH, the OH adduct may react with a proton followed by water elimination, may add OH- or react with water followed by elimination of a proton. The pA" values for the equilibria Me('l+‘)+ = Mc(OH)n+ ~ Me(OH)O-1)4 decrease with increasing state of oxidation of Me. The oxidative properties decrease with increasing state of hydrolysis. | en_US |
dc.language.iso | en | en_US |
dc.publisher | Journal of the Chemical Society : Faraday Transaction - I. The Chemical Society, London. 1978, 74 (08) | en_US |
dc.subject | Chemistry | en_US |
dc.subject | Hydrolysis | en_US |
dc.subject | Journal of the Chemical Society : Faraday Transaction - I | en_US |
dc.title | On the Hydrolysis of Agn, T1H, Sn111 and CuI[1 | en_US |
dc.type | Article | en_US |
Appears in Collections: | Journal Articles (before-1995) |
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File | Description | Size | Format | |
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1820-1826-x.pdf Restricted Access | 449.17 kB | Adobe PDF | View/Open Request a copy |
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