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dc.contributor.authorAsmus, Klaus-Dieter-
dc.contributor.authorToffel, Peter-
dc.contributor.authorBonifacio, Marija-
dc.date.accessioned2025-05-06T11:09:34Z-
dc.date.available2025-05-06T11:09:34Z-
dc.date.issued1978-
dc.identifier.urihttp://dspace.bits-pilani.ac.in:8080/jspui/handle/123456789/18861-
dc.description.abstractUsing pulse radiolysis with optical, conductometric and polarographic detection it is shown that the oxidation of T1+, Ag+, Cu2 ! and Sn2 ■ by hydroxyl radicals proceeds via on OH adduct: Mc"+ + •OH Me(OH)'l+. Depending on pH, the OH adduct may react with a proton followed by water elimination, may add OH- or react with water followed by elimination of a proton. The pA" values for the equilibria Me('l+‘)+ = Mc(OH)n+ ~ Me(OH)O-1)4 decrease with increasing state of oxidation of Me. The oxidative properties decrease with increasing state of hydrolysis.en_US
dc.language.isoenen_US
dc.publisherJournal of the Chemical Society : Faraday Transaction - I. The Chemical Society, London. 1978, 74 (08)en_US
dc.subjectChemistryen_US
dc.subjectHydrolysisen_US
dc.subjectJournal of the Chemical Society : Faraday Transaction - Ien_US
dc.titleOn the Hydrolysis of Agn, T1H, Sn111 and CuI[1en_US
dc.typeArticleen_US
Appears in Collections:Journal Articles (before-1995)

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