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Please use this identifier to cite or link to this item: http://dspace.bits-pilani.ac.in:8080/jspui/handle/123456789/18870
Title: Effect of Viscosity on the Bimolecular Termination Rate Constants for Semiquinone Radicals in Solution: a Kinetic E.S.R. Study
Authors: Elliot, John
Egan, Karen L.
Wan, Jeffrey K. S.
Keywords: Chemistry
bimolecular termination rate constants
Journal of the Chemical Society : Faraday Transaction - I
Issue Date: 1978
Publisher: Journal of the Chemical Society : Faraday Transaction - I. The Chemical Society, London. 1978, 74 (08)
Abstract: The Arrhenius activation energies (EA) have been determined for the near diffusion-controlled bimolecular termination reactions of some semiquinone radicals in a series of solvents. It was often found that EA was less than the activation energy of diffusion (ED) is the solvent. An explanation has been proposed in terms of the rate of encounters between the radicals and the rate at which the radicals react during an encounter.
URI: http://dspace.bits-pilani.ac.in:8080/jspui/handle/123456789/18870
Appears in Collections:Journal Articles (before-1995)

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