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http://dspace.bits-pilani.ac.in:8080/jspui/handle/123456789/18889| Title: | Mechanism of thermolysis of tetramethylsilane and trimethylsilane |
| Authors: | Baldwin, Alan C. Davidson, Iain M. T. Reed, Michael D. |
| Keywords: | Chemistry Thermolysis of tetramethylsilane thermolysis of trimethylsilane Journal of the Chemical Society : Faraday Transaction - I |
| Issue Date: | 1978 |
| Publisher: | Journal of the Chemical Society : Faraday Transaction - I. The Chemical Society, London. 1978, 74 (09-12) |
| Abstract: | The thermolysis of tetramethylsilane has been studied in a pulsed stirred-flow system between 840 and 1055 K, yielding significantly different Arrhenius parameters above and below 950 K. The high temperature results relate to a non-chain mechanism, whence D(Me3Si–Me)= 355 ± 6 kJ mol–1 while the low temperature results relate to a short chain sequence. A mechanism for the latter is shown by computer-aided numerical integration to be consistent with experimental results, as is a similar chain mechanism for the thermolysis of trimethylsilane. |
| URI: | http://dspace.bits-pilani.ac.in:8080/jspui/handle/123456789/18889 |
| Appears in Collections: | Journal Articles (before-1995) |
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| File | Description | Size | Format | |
|---|---|---|---|---|
| 2171-2178.pdf Restricted Access | 473.81 kB | Adobe PDF | View/Open Request a copy |
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