Please use this identifier to cite or link to this item:
http://dspace.bits-pilani.ac.in:8080/jspui/handle/123456789/18899| Title: | Self-reactions of Isopropylperoxy Radicals in the Gas Phase |
| Authors: | Kirsch, Leslie J. Parkes, David A. Waddington, David J. Woolley, Allan |
| Keywords: | Chemistry Isopropylperoxy radical Journal of the Chemical Society : Faraday Transaction - I |
| Issue Date: | 1978 |
| Publisher: | Journal of the Chemical Society : Faraday Transaction - I. The Chemical Society, London. 1978, 74 (09-12) |
| Abstract: | The photo-oxidation of 2,2′-azopropane has been studied in order to determine the overall rate constant for the second-order removal of isopropylperoxy radicals. Arrhenius parameters of log10(Aobs/dm3 mol–1 s–1)= 9.15 ± 0.03 and Eobs= 18.65 ± 0.50 kJ mol–1 have been determined over a temperature range 300–373 K. These values are compared with those obtained for the self-reactions of primary and tertiary alkylperoxyradicals, and the corresponding reactions in solution. |
| URI: | http://dspace.bits-pilani.ac.in:8080/jspui/handle/123456789/18899 |
| Appears in Collections: | Journal Articles (before-1995) |
Files in This Item:
| File | Description | Size | Format | |
|---|---|---|---|---|
| 2293-2300.pdf Restricted Access | 491.35 kB | Adobe PDF | View/Open Request a copy |
Items in DSpace are protected by copyright, with all rights reserved, unless otherwise indicated.