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http://dspace.bits-pilani.ac.in:8080/jspui/handle/123456789/18900| Title: | Reactions of Alkyl Radicals with Nitrogen Trifluoride |
| Authors: | Cadman, Philip Inel, Yuksel Trotman-Dickenson, Aubrey F. |
| Keywords: | Chemistry Nitrogen trifluoride Journal of the Chemical Society : Faraday Transaction - I |
| Issue Date: | 1978 |
| Publisher: | Journal of the Chemical Society : Faraday Transaction - I. The Chemical Society, London. 1978, 74 (09-12) |
| Abstract: | Photolysis of mixtures of nitrogen trifluoride with the appropriate ketones (in the temperature range 303–486 K) has enabled the reactions of CH3, CF3, C2H5, i-C3H7 and t-C4H9 radicals with nitrogen trifluoride to be studied. With the smaller radicals only the abstraction of difluoroamino radicals is important, but with i-C3H7 and t-butyl both difluoroamino and fluorine abstraction occur. The Arrhenius parameters are given. The disproportionation—combination ratio for methyl and t-butyl radicals was found to be 0.83 ± 0.02. |
| URI: | http://dspace.bits-pilani.ac.in:8080/jspui/handle/123456789/18900 |
| Appears in Collections: | Journal Articles (before-1995) |
Files in This Item:
| File | Description | Size | Format | |
|---|---|---|---|---|
| 2301-2312.pdf Restricted Access | 700.48 kB | Adobe PDF | View/Open Request a copy |
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