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Please use this identifier to cite or link to this item: http://dspace.bits-pilani.ac.in:8080/jspui/handle/123456789/18967
Title: Kinetics of the Thermal Isomerisation of Hexamethyldisilane
Authors: Davidson, Iain M. T.
Keywords: Chemistry
Kinetics
Hexamethyldisilane
Journal of the Chemical Society : Faraday Transaction - I
Issue Date: 1974
Publisher: Journal of the Chemical Society : Faraday Transaction - I. The Chemical Society, London. 1974, 70 (1-6)
Abstract: A kinetic investigation of the gas-phase isomerisation of hexamethyldisilane between 717 and 780 K with initial pressures of 10-125 mmHg is described, and discussed in relation to other work on the thermolysis of hexamethyldisilane. The isomerisation is a radical chain reaction of three halves order, with rate constants given by Xr/cmJ moH s-' = iol6-6s±o-7O exp[— (251 ± 8)/2?T] (activation energy in kJ mol-1).
URI: http://dspace.bits-pilani.ac.in:8080/jspui/handle/123456789/18967
Appears in Collections:Journal Articles (before-1995)

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