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Title: | Kinetics of the Thermal Isomerisation of Hexamethyldisilane |
Authors: | Davidson, Iain M. T. |
Keywords: | Chemistry Kinetics Hexamethyldisilane Journal of the Chemical Society : Faraday Transaction - I |
Issue Date: | 1974 |
Publisher: | Journal of the Chemical Society : Faraday Transaction - I. The Chemical Society, London. 1974, 70 (1-6) |
Abstract: | A kinetic investigation of the gas-phase isomerisation of hexamethyldisilane between 717 and 780 K with initial pressures of 10-125 mmHg is described, and discussed in relation to other work on the thermolysis of hexamethyldisilane. The isomerisation is a radical chain reaction of three halves order, with rate constants given by Xr/cmJ moH s-' = iol6-6s±o-7O exp[— (251 ± 8)/2?T] (activation energy in kJ mol-1). |
URI: | http://dspace.bits-pilani.ac.in:8080/jspui/handle/123456789/18967 |
Appears in Collections: | Journal Articles (before-1995) |
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