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http://dspace.bits-pilani.ac.in:8080/jspui/handle/123456789/18979| Title: | Kinetics of the Thermal Gas-phase Decomposition of 6-Oxabicyclo[3,1,0]hexane |
| Authors: | Flowers, Michael C. Penny, David E. |
| Keywords: | Chemistry Kinetics Thermal Gas-phase Decomposition Journal of the Chemical Society : Faraday Transaction - I |
| Issue Date: | 1974 |
| Publisher: | Journal of the Chemical Society : Faraday Transaction - I. The Chemical Society, London. 1974, 70 (1-6) |
| Abstract: | The kinetics of the gas-phase decomposition of 6-oxabicyclo[3,l,0jhcxanc have been studied over the temperature range 670-742 K. at pressures between 1 and 28 Torr. Isomerization to cyclopcnta- nonc and cyclopcnt-2-en-l-ol accounts for —97 of the primary reaction products and occurs by tirst-ordcr, homogeneous, non-radical processes. A'cyclopcntanonc/s-1 = 1014'10 + 11 cxp(-240 400 + 1500/8.314T) A-cyelorcnt^-en-i-ol/s-1 = 10‘3-5" T°-1" cxpf-242 200 + 2200/8.314T) |
| URI: | http://dspace.bits-pilani.ac.in:8080/jspui/handle/123456789/18979 |
| Appears in Collections: | Journal Articles (before-1995) |
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| File | Description | Size | Format | |
|---|---|---|---|---|
| 355-361.pdf Restricted Access | 530.78 kB | Adobe PDF | View/Open Request a copy |
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