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http://dspace.bits-pilani.ac.in:8080/jspui/handle/123456789/18991| Title: | Radiolysis of Pyrimidines in Aqueous Solutions: Part 2.—Product Formation in the Interaction of ea~, -H, -OH and C17- with |
| Authors: | Infante, Gabriel A. Jirathana, Poonsri Fendler, Eleanor J. Fendler, Janos H. |
| Keywords: | Chemistry Radiolysis of Pyrimidines Aqueous Solutions Journal of the Chemical Society : Faraday Transaction - I |
| Issue Date: | 1974 |
| Publisher: | Journal of the Chemical Society : Faraday Transaction - I. The Chemical Society, London. 1974, 70 (07) |
| Abstract: | Product yields in the reaction of e~, -H, -OH and Cl/ with uracil and uracil- have been determined quantitatively in 60Co y-irradiated aqueous uracil solutions in the presence of suitable scavengers. Good material balances between G(—uracil) and G(total products) have been obtained in all cases. The products determined were: uracil dimer, alloxan, alloxantin, uracil czj-glycol, uracil /ra/u-glycol, dialuric acid, isobarbituric acid, 5-hydroxydihydrouraciI, 6-hydroxydihydrouraciI, dihydrouracil, formylurea, 5-hydroxyhydantoin, parabanic acid, urea and alcohol adducts. Based on the yields of these products and the available literature, mechanisms are proposed and discussed. |
| URI: | http://dspace.bits-pilani.ac.in:8080/jspui/handle/123456789/18991 |
| Appears in Collections: | Journal Articles (before-1995) |
Files in This Item:
| File | Description | Size | Format | |
|---|---|---|---|---|
| 1162-1170.pdf Restricted Access | 704.98 kB | Adobe PDF | View/Open Request a copy |
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