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Please use this identifier to cite or link to this item: http://dspace.bits-pilani.ac.in:8080/jspui/handle/123456789/18999
Title: Probability of Reaction of H with N2O as a Function of Energy
Authors: Oldershaw, G. A.
Porter, D. A.
Keywords: Chemistry
Probability of Reaction
Function of Energy
Journal of the Chemical Society : Faraday Transaction - I
Issue Date: 1974
Publisher: Journal of the Chemical Society : Faraday Transaction - I. The Chemical Society, London. 1974, 70 (07)
Abstract: The net probabilities of reactions (1) and (2) have been determined as a function of the initial kinetic energy of H* by analysis of the products of photolysis, at various wavelengths, of Hl mixed with N2O. H* + N2O->N2 + OH H* + N2O->NO + NH (1) (2) Reaction (1) is predominant at all energies studied. The results have been used to calculate a crude excitation function for reaction (1), which has a maximum cross section of about 6x 10“ 3 nm2. By using the excitation function to calculate rate coefficients, which are in good agreement with experimental values, the hot atom results arc shown to be consistent with measurements of the rate of (1) in thermal systems at high temperatures.
URI: http://dspace.bits-pilani.ac.in:8080/jspui/handle/123456789/18999
Appears in Collections:Journal Articles (before-1995)

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