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Title: | Photolysis of Cycloheptanon |
Authors: | Frey, Henry M. Mautner, Gillian N. |
Keywords: | Chemistry Photolysis Cycloheptanon Journal of the Chemical Society : Faraday Transaction - I |
Issue Date: | 1974 |
Publisher: | Journal of the Chemical Society : Faraday Transaction - I. The Chemical Society, London. 1974, 70 (07) |
Abstract: | The photochemical decomposition of cyclohcptanonc lias been studied in the gas phase as a function of pressure, temperature and wavelength. The major products arc carbon monoxide, hcx-l-cnc, cyclohexane and hcpt-6-enal. Quantum yields of the hydrocarbons and aldehyde were determined at 313 nm and 100'C over a range of ketone pressures. The results indicate that the hydrocarbons have a common precursor and that they arc produced by a higher energy pathway than the aldehyde. A mechanism involving a triplet state intermediate is suggested. |
URI: | http://dspace.bits-pilani.ac.in:8080/jspui/handle/123456789/19005 |
Appears in Collections: | Journal Articles (before-1995) |
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1299-1305.pdf Restricted Access | 391.65 kB | Adobe PDF | View/Open Request a copy |
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