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Please use this identifier to cite or link to this item: http://dspace.bits-pilani.ac.in:8080/jspui/handle/123456789/19005
Title: Photolysis of Cycloheptanon
Authors: Frey, Henry M.
Mautner, Gillian N.
Keywords: Chemistry
Photolysis
Cycloheptanon
Journal of the Chemical Society : Faraday Transaction - I
Issue Date: 1974
Publisher: Journal of the Chemical Society : Faraday Transaction - I. The Chemical Society, London. 1974, 70 (07)
Abstract: The photochemical decomposition of cyclohcptanonc lias been studied in the gas phase as a function of pressure, temperature and wavelength. The major products arc carbon monoxide, hcx-l-cnc, cyclohexane and hcpt-6-enal. Quantum yields of the hydrocarbons and aldehyde were determined at 313 nm and 100'C over a range of ketone pressures. The results indicate that the hydrocarbons have a common precursor and that they arc produced by a higher energy pathway than the aldehyde. A mechanism involving a triplet state intermediate is suggested.
URI: http://dspace.bits-pilani.ac.in:8080/jspui/handle/123456789/19005
Appears in Collections:Journal Articles (before-1995)

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