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Title: | Solid/Liquid Phase Equilibria and Solid Compound Formation in Mixtures of Hexafluorobenzene with Nitrogen Containing Compounds |
Authors: | Ott, J. Bevan Goates, J. Rex Reeder, Joan Shirts, Randall B. |
Keywords: | Chemistry Solid/Liquid Phase Equilibria Solid Compound Formation Journal of the Chemical Society : Faraday Transaction - I |
Issue Date: | 1974 |
Publisher: | Journal of the Chemical Society : Faraday Transaction - I. The Chemical Society, London. 1974, 70 (07) |
Abstract: | Thermal methods have been used to determine with high precision the solid/liqnid phase equilibria diagrams tor mixtures of hcxafluorobcnzene with Y-methylmorpholine, TV-methyipipcridinc and AW'-dimcthylpiperazine. Solid addition compounds form in all three systems. Exploratory measurements show that hcxafluorobcnzene docs not form solid addition compounds with triethyl amine, acetonitrile or AW-dimcthylacetamide. A comparison of the phase diagrams for a number of systems containing hcxafluorobcnzene suggests that compound formation with hcxafluorobcnzene results from a combination of favorable packing geometry and electrostatic interactions. |
URI: | http://dspace.bits-pilani.ac.in:8080/jspui/handle/123456789/19008 |
Appears in Collections: | Journal Articles (before-1995) |
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