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Please use this identifier to cite or link to this item: http://dspace.bits-pilani.ac.in:8080/jspui/handle/123456789/19008
Title: Solid/Liquid Phase Equilibria and Solid Compound Formation in Mixtures of Hexafluorobenzene with Nitrogen Containing Compounds
Authors: Ott, J. Bevan
Goates, J. Rex
Reeder, Joan
Shirts, Randall B.
Keywords: Chemistry
Solid/Liquid Phase Equilibria
Solid Compound Formation
Journal of the Chemical Society : Faraday Transaction - I
Issue Date: 1974
Publisher: Journal of the Chemical Society : Faraday Transaction - I. The Chemical Society, London. 1974, 70 (07)
Abstract: Thermal methods have been used to determine with high precision the solid/liqnid phase equilibria diagrams tor mixtures of hcxafluorobcnzene with Y-methylmorpholine, TV-methyipipcridinc and AW'-dimcthylpiperazine. Solid addition compounds form in all three systems. Exploratory measurements show that hcxafluorobcnzene docs not form solid addition compounds with triethyl amine, acetonitrile or AW-dimcthylacetamide. A comparison of the phase diagrams for a number of systems containing hcxafluorobcnzene suggests that compound formation with hcxafluorobcnzene results from a combination of favorable packing geometry and electrostatic interactions.
URI: http://dspace.bits-pilani.ac.in:8080/jspui/handle/123456789/19008
Appears in Collections:Journal Articles (before-1995)

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