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Please use this identifier to cite or link to this item: http://dspace.bits-pilani.ac.in:8080/jspui/handle/123456789/19031
Title: Interaction between Silver Iodide Surfaces in the Presence of Specifically Adsorbed Ions
Authors: Melville, James B.
Smith, Alec L.
Keywords: Chemistry
Silver Iodide Surfaces
Adsorbed Ions
Journal of the Chemical Society : Faraday Transaction - I
Issue Date: 1974
Publisher: Journal of the Chemical Society : Faraday Transaction - I. The Chemical Society, London. 1974, 70 (08)
Abstract: Interaction pressures between approaching identical semi-infinite plates are examined for Agl in aqueous solution in the cases of constant Ag+/I~ charge, constant total charge, constant wall potential 0o and constant diffuse layer potential 0d. For this purpose the adsorption isotherm for K+ ions on silver iodide is taken from a combination of potentiometric titration and electrokinetic data. The physically unrealistic result of repulsive pressures tending to infinite values at short separations, which occurs for constant total charge, is shown not to occur for constant surface charge when the adsorbed charge due to indifferent counter ions can equilibrate on approach.
URI: http://dspace.bits-pilani.ac.in:8080/jspui/handle/123456789/19031
Appears in Collections:Journal Articles (before-1995)

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