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Please use this identifier to cite or link to this item: http://dspace.bits-pilani.ac.in:8080/jspui/handle/123456789/19071
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dc.contributor.authorKumar, Anil-
dc.date.accessioned2025-07-24T06:39:54Z-
dc.date.available2025-07-24T06:39:54Z-
dc.date.issued2024-08-
dc.identifier.urihttps://advanced.onlinelibrary.wiley.com/doi/full/10.1002/adsc.202400755-
dc.identifier.urihttp://dspace.bits-pilani.ac.in:8080/jspui/handle/123456789/19071-
dc.description.abstractA visible-light-promoted site-selective difluoroalkoxylation of imidazo[1,2-a]pyridines has been achieved using N-fluorobenzenesulfonimide (NFSI) as a fluorinating agent. This practical reaction has a wide range of substrate scope for both imidazo[1,2-a]pyridines and alcohols to give 3,3-difluoro-2-alkoxy-2-arylimidazo[1,2-a]pyridines in 65–93% yields. The reaction proceeded at room temperature, showed high functional group tolerance, and was amenable to scale-up. Based on mechanistic investigation, a radical pathway is proposed.en_US
dc.language.isoenen_US
dc.publisherWileyen_US
dc.subjectChemistryen_US
dc.subjectVisible-light photoredox catalysisen_US
dc.subjectImidazo[1,2-a]pyridinesen_US
dc.subjectFluorinationen_US
dc.subjectRadical pathwayen_US
dc.titleVisible light-driven difluoroalkoxylation of imidazopyridines using n-fluorobenzenesulfonimide as fluorinating agenten_US
dc.typeArticleen_US
Appears in Collections:Department of Chemistry

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