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Please use this identifier to cite or link to this item: http://dspace.bits-pilani.ac.in:8080/jspui/handle/123456789/20048
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dc.contributor.authorFarrington, John A.-
dc.contributor.authorEbert, Michael-
dc.contributor.authorLand, Edward J.-
dc.date.accessioned2025-11-15T06:08:06Z-
dc.date.available2025-11-15T06:08:06Z-
dc.date.issued1978-
dc.identifier.urihttp://dspace.bits-pilani.ac.in:8080/jspui/handle/123456789/20048-
dc.descriptionDecay curves have been measured for reaction with oxygen of radicals derived by pulse radiolysis from a series of bipyridylium salts. The shapes of the curves were consistent with decay due to reaction of the bipyridyl radicals with both oxygen and superoxide ion, and rate constants k1 and k2 for these reactions were estimated. For compounds with redox potentials above –0.2 V, the reverse reaction, between superoxide ion and bipyridylium salt, was included in the kinetic scheme. k1 values were mostly between 4 and 9 × 108 dm3 mol–1 s–1 and k2 values were all higher. The correlation of rate constants with difference between redox potentials of donor and acceptor is discussed.en_US
dc.language.isoenen_US
dc.publisherJournal of the Chemical Society : Faraday Transaction - I. The Chemical Society, London. 1978, 74 (3)en_US
dc.subjectChemistryen_US
dc.subjectBipyridylium quaternary saltsen_US
dc.subjectPulse radiolysisen_US
dc.subjectJournal of the Chemical Society : Faraday Transaction - Ien_US
dc.titleBipyridylium Quaternary Salts and Related Compounds: Part 6.—Pulse Radiolysis Studies of the Reaction of Paraquat Radical Analogues with Oxygenen_US
dc.typeArticleen_US
Appears in Collections:Journal Articles (before-1995)

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