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http://dspace.bits-pilani.ac.in:8080/jspui/handle/123456789/20132| Title: | Heats of Mixing and the Solid-State Transition in [(C6H5)3PCH3]1– +x[(C6H5)3AsCH3] +x(TCNQ) –2, (0 ⩽×⩽ 1), Anion Radical Salts |
| Authors: | Iida, Yôichi |
| Keywords: | Journal of the Chemical Society : Faraday Transaction - I Chemistry Solid-State Transition Anion Radical Salts |
| Issue Date: | 1978 |
| Publisher: | Journal of the Chemical Society : Faraday Transaction - I. The Chemical Society, London. 1978, 74 (1) |
| Abstract: | The phase transitions of solid solutions were investigated with the anion radical salts of [(C6H5)3PCH3]1–+x[(C6H5)3AsCH3]+x(TCNQ)–[graphic omitted], (0 ⩽×⩽ 1). The behaviour of the phase transitions with respect to the composition parameter (x) was studied by using a regular binary solid solution model. It was found that the difference in the heats of mixing between the low-temperature (αγ) and high-temperature (βγ) phases of the solid solutions was very important in the explanation of the line shape of the observed phase diagram. |
| URI: | http://dspace.bits-pilani.ac.in:8080/jspui/handle/123456789/20132 |
| Appears in Collections: | Journal Articles (before-1995) |
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| File | Description | Size | Format | |
|---|---|---|---|---|
| 0190-0194.pdf Restricted Access | 263.49 kB | Adobe PDF | View/Open Request a copy |
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