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http://dspace.bits-pilani.ac.in:8080/jspui/handle/123456789/20145| Title: | Transport in Aqueous Solutions of Group IIB Metal Salts at 298.15 K Part 5.—Irreversible Thermodynamic Parameters for Zinc Perchlorate and Verification of Onsager’s Reciprocal Relationships |
| Authors: | Agnew, Andrew Paterson, Russell |
| Keywords: | Chemistry Zinc perchlorate Transport properties Journal of the Chemical Society : Faraday Transaction - I |
| Issue Date: | 1978 |
| Publisher: | Journal of the Chemical Society : Faraday Transaction - I. The Chemical Society, London. 1978, 74 (09-12) |
| Abstract: | The isothermal vectorial transport properties of zinc perchlorate have been measured over the concentration range 0.1–3.0 mol dm–3 at 298.15 K. Hittorf transport numbers were shown to agree with those measured earlier using concentration cells. Conductance and salt diffusion coefficients were also measured. These data were used to calculate mobility (Lik) and resistance (Rik) coefficients using irreversible thermodynamic theory. Analysis showed that the Onsager reciprocal relationships (O.R.R.) were obeyed. |
| URI: | http://dspace.bits-pilani.ac.in:8080/jspui/handle/123456789/20145 |
| Appears in Collections: | Journal Articles (before-1995) |
Files in This Item:
| File | Description | Size | Format | |
|---|---|---|---|---|
| 2885-2895.pdf Restricted Access | 721.36 kB | Adobe PDF | View/Open Request a copy |
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