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http://dspace.bits-pilani.ac.in:8080/jspui/handle/123456789/20158| Title: | Thermodynamic Properties of Hydrogen in Palladium and its Alloys under Conditions of Constant Volume |
| Authors: | Oates, W. Alan Flanagan, Ted B |
| Keywords: | Chemistry Thermodynamic properties Palladium Journal of the Chemical Society : Faraday Transaction - I |
| Issue Date: | 1977 |
| Publisher: | Journal of the Chemical Society : Faraday Transaction - I. The Chemical Society, London. 1977, 73 (07) |
| Description: | Thermodynamic properties for the solution of hydrogen in palladium and its alloys are experimentally determined under conditions of constant pressure (corresponding to a free surface solid). In this research these data are converted to conditions of constant alloy volume. For palladium/hydrogen it is predicted that the phase change, α→β, which is so characteristic of this system, no longer appears under conditions of constant volume. This is indicative of the fact that long range dipole-dipole elastic interactions predominate in this system. A different sequence of behaviour of ΔµxsH→0 values with atom fraction of substituted metal is predicted for alloys of the type palladium + group IB for constant volume conditions as compared with conditions of constant pressure. |
| URI: | http://dspace.bits-pilani.ac.in:8080/jspui/handle/123456789/20158 |
| Appears in Collections: | Journal Articles (before-1995) |
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|---|---|---|---|---|
| 0993-1002.pdf Restricted Access | 797.38 kB | Adobe PDF | View/Open Request a copy |
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