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http://dspace.bits-pilani.ac.in:8080/jspui/handle/123456789/20187| Title: | Washburn Numbers: Part 3.—Alkali-metal Chlorides in the DMSO4-Water System; Comparison with Hydrochloric Acid ; “ Structural ” Effects |
| Authors: | Feakins, David O’Shaughnessy, Denis A. |
| Keywords: | Journal of the Chemical Society : Faraday Transaction - I Chemistry Washburn Numbers Alkali-metal Chlorides |
| Issue Date: | 1978 |
| Publisher: | Journal of the Chemical Society : Faraday Transaction - I. The Chemical Society, London. 1978, 74 (02) |
| Abstract: | Washburn numbers for alkali-metal chlorides have been measured in the range 0-40 % (w/w) DMSO (x2 = 0-0.094) and are compared with literature values for H+CI-. There is evidence for significant incorporation of DMSO into near-neighbour shells of H+ and Li+; by making certain assumptions it is concluded that these ions, and Cl-, are preferentially solvated by DMSO. The Washburn numbers of H+Cl, LrCl- and K+Cl- show maxima when plotted against ,v2. Possible explanations of this behaviour, which is paralleled by that of the Walden products, are discussed in detail, and it is concluded that it arises mainly from shifts in the preferential rather than the total solvation of the ions. The maxima in are evidence for the retention of water-like structure in the region studied, but not necessarily for its enhancement. |
| URI: | http://dspace.bits-pilani.ac.in:8080/jspui/handle/123456789/20187 |
| Appears in Collections: | Journal Articles (before-1995) |
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| File | Description | Size | Format | |
|---|---|---|---|---|
| 0380-0392.pdf Restricted Access | 1 MB | Adobe PDF | View/Open Request a copy |
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