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Please use this identifier to cite or link to this item: http://dspace.bits-pilani.ac.in:8080/jspui/handle/123456789/20192
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dc.contributor.authorGans, Peter-
dc.contributor.authorGill, J. Bernard-
dc.contributor.authorGriffin, Mervyn-
dc.date.accessioned2025-11-21T14:23:35Z-
dc.date.available2025-11-21T14:23:35Z-
dc.date.issued1978-
dc.identifier.urihttp://dspace.bits-pilani.ac.in:8080/jspui/handle/123456789/20192-
dc.description.abstractA detailed study of the Raman spectra of mixtures of AgNO3 and KSCN in liquid ammonia solution indicates the formation of a weak S-bonded 1: 1 complex between Ag ■ and SCN-. Formation constants (concentration quotients) arc 3.1±0.5 and 1.3 ±0.4 kg mob1 at 293 and 233 K respectively. The formation of AgSCN is entropy favoured (±5 ~ 37 J mol-1 K-1) but enthalpy hindered (A 7/ ~ 8.2 kJ mol-1); the equilibrium [Ag(NH3)4]++SCN- [Ag(NH3)3SCN] + NH3 is proposed on the basis of these results. The possible existence of species such as [Ag2SCN]+ and [Ag(SCN)2]~ is suggested by some minor spectral features.en_US
dc.language.isoenen_US
dc.publisherJournal of the Chemical Society : Faraday Transaction - I. The Chemical Society, London. 1978, 74 (02)en_US
dc.subjectJournal of the Chemical Society : Faraday Transaction - Ien_US
dc.subjectChemistryen_US
dc.subjectSpectrochemistryen_US
dc.subjectLiquid Ammoniaen_US
dc.titleSpectrochemistry of Solutions: Part 5.1—Raman Spectroscopic Study of the Coordination of Silver(i) Ions in Liquid Ammonia by Thiocyanate lonsen_US
dc.typeArticleen_US
Appears in Collections:Journal Articles (before-1995)

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