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Please use this identifier to cite or link to this item: http://dspace.bits-pilani.ac.in:8080/jspui/handle/123456789/20202
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dc.contributor.authorBayliss, Stuart G.-
dc.contributor.authorFailes, Robert L.-
dc.contributor.authorShapiro, Jacob S.-
dc.date.accessioned2025-11-21T18:01:06Z-
dc.date.available2025-11-21T18:01:06Z-
dc.date.issued1978-
dc.identifier.urihttp://dspace.bits-pilani.ac.in:8080/jspui/handle/123456789/20202-
dc.description.abstractGas phase photolysis of neopentyl bromide was studied over the temperature range 478-564 K. The major products were hydrogen bromide, 1,1-dimethylcyclopropane, with smaller amounts of methylbutenes and neopentane. Above initial reactant pressures of 50 kPa the overall rate expression is given by: -d[npb]/dr = A-[npb] I°-\ where Io is the incident light intensity. The overall activation energy is 58.5 kJ mol-1. The principal propagation step is the cyclisation of the 3-bromo-2,2-dimethylpropyl radical to 1 1- dimethylcyclopropane and a bromine atom.en_US
dc.language.isoenen_US
dc.publisherJournal of the Chemical Society : Faraday Transaction - I. The Chemical Society, London. 1978, 74 (04)en_US
dc.subjectJournal of the Chemical Society : Faraday Transaction - Ien_US
dc.subjectChemistryen_US
dc.subjectCyclisationen_US
dc.subjectGas Phase Photolysisen_US
dc.subjectNeopentyl Bromideen_US
dc.titleCyclisation in the Gas Phase Photolysis of Neopentyl Bromideen_US
dc.typeArticleen_US
Appears in Collections:Journal Articles (before-1995)

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