Please use this identifier to cite or link to this item:
http://dspace.bits-pilani.ac.in:8080/jspui/handle/123456789/20303| Title: | Reaction, of Oxygen Atoms with Methyl and Ethyl Nitrates |
| Authors: | Salter, Leo F. Thrush, Brian A. |
| Keywords: | Chemistry Oxygen atoms Ethyl Nitrates Journal of the Chemical Society : Faraday Transaction - I |
| Issue Date: | 1977 |
| Publisher: | Journal of the Chemical Society : Faraday Transaction - I. The Chemical Society, London. 1977, 73 (07) |
| Abstract: | The reaction of oxygen atoms with methyl nitrate and with ethyl nitrate have been studied in a discharge–flow system at temperatures between 294 and 473 K. The initial attack involves abstraction of a hydrogen atom for which the rate expressions are shown to be 1.5 × 1010 exp (–22.0 ± 1.0 kJ mol–1/RT) dm3 mol–1 s–1 and 2.6 × 1010 exp (–21.6 ± 2.6 kJ mol–1/RT) dm3 mol–1 s–1 respectively. The activation energy for hydrogen abstraction is not reduced by the fact that the initially formed radical ruptures exothermically to yield an aldehyde plus nitrogen dioxide. |
| URI: | http://dspace.bits-pilani.ac.in:8080/jspui/handle/123456789/20303 |
| Appears in Collections: | Journal Articles (before-1995) |
Files in This Item:
| File | Description | Size | Format | |
|---|---|---|---|---|
| 1098-1103.pdf Restricted Access | 423.61 kB | Adobe PDF | View/Open Request a copy |
Items in DSpace are protected by copyright, with all rights reserved, unless otherwise indicated.