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http://dspace.bits-pilani.ac.in:8080/jspui/handle/123456789/20426| Title: | Slow Gas-Phase Oxidation of Ethylal with C-14 as a Tracer |
| Authors: | Molera, Maria J Garcia-Dominguez, Jose A Lopez, Alvaro Rodriguez Santiuste, Jose M |
| Keywords: | Chemistry Gas-phase oxidation Reaction kinetics Journal of the Chemical Society : Faraday Transaction - I |
| Issue Date: | 1977 |
| Publisher: | Journal of the Chemical Society : Faraday Transaction - I. The Chemical Society, London. 1977, 73 (12) |
| Abstract: | The slow gas-phase oxidation of ethylal was investigated at low temperatures (160–190°C) by the static method. The main products were carbon oxides, water, acetaldehyde, acetic acid, ethanol and ethyl formate with some methanol, formaldehyde, formic acid, n-butane, ethylene and peroxides. Three different ethylal samples labelled with C-14 in each one of its three different positions, respectively, have been synthesized; their oxidation has been studied and the reaction products analysed by radiochromatography. A mechanism is suggested where the branching intermediates are hydroperoxides derived from ethylal. |
| URI: | http://dspace.bits-pilani.ac.in:8080/jspui/handle/123456789/20426 |
| Appears in Collections: | Journal Articles (before-1995) |
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| File | Description | Size | Format | |
|---|---|---|---|---|
| 1900-1906.pdf Restricted Access | 455.02 kB | Adobe PDF | View/Open Request a copy |
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