Inter-ligand azo (N[double bond, length as m-dash]N) unit formation and stabilization of a Co(ii)-diradical complex via metal-to-ligand dπ–pπ* back donation: synthesis, characterization, and theoretical study

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Title:	Inter-ligand azo (N[double bond, length as m-dash]N) unit formation and stabilization of a Co(ii)-diradical complex via metal-to-ligand dπ–pπ* back donation: synthesis, characterization, and theoretical study
Authors:	Roy, Ram Kinkar
Keywords:	Chemistry Inter-ligand azo
Issue Date:	2015
Publisher:	ACS
Abstract:	An azide (–N3) group attached at the -ortho carbon atom to the aniline moiety of 2-anilino-4,6-di-tert-butylphenol formed a diradical-containing Co(II) complex via inter-ligand azo (N[double bond, length as m-dash]N) bond formation. Metal-to-ligand (azo), dπ-to-pπ* back donation stabilized the metal in its lower oxidation state.
URI:	https://pubs.rsc.org/en/content/articlelanding/2015/DT/C4DT03214D http://dspace.bits-pilani.ac.in:8080/xmlui/handle/123456789/2725
Appears in Collections:	Department of Chemistry

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