Inter-ligand azo (N[double bond, length as m-dash]N) unit formation and stabilization of a Co(ii)-diradical complex via metal-to-ligand dπ–pπ* back donation: synthesis, characterization, and theoretical study

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DC Field	Value	Language
dc.contributor.author	Roy, Ram Kinkar	-
dc.date.accessioned	2021-10-12T11:32:39Z	-
dc.date.available	2021-10-12T11:32:39Z	-
dc.date.issued	2015	-
dc.identifier.uri	https://pubs.rsc.org/en/content/articlelanding/2015/DT/C4DT03214D	-
dc.identifier.uri	http://dspace.bits-pilani.ac.in:8080/xmlui/handle/123456789/2725	-
dc.description.abstract	An azide (–N3) group attached at the -ortho carbon atom to the aniline moiety of 2-anilino-4,6-di-tert-butylphenol formed a diradical-containing Co(II) complex via inter-ligand azo (N[double bond, length as m-dash]N) bond formation. Metal-to-ligand (azo), dπ-to-pπ* back donation stabilized the metal in its lower oxidation state.	en_US
dc.language.iso	en	en_US
dc.publisher	ACS	en_US
dc.subject	Chemistry	en_US
dc.subject	Inter-ligand azo	en_US
dc.title	Inter-ligand azo (N[double bond, length as m-dash]N) unit formation and stabilization of a Co(ii)-diradical complex via metal-to-ligand dπ–pπ* back donation: synthesis, characterization, and theoretical study	en_US
dc.type	Article	en_US
Appears in Collections:	Department of Chemistry

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