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Title: | C–H⋯Cl− hydrogen bonds in solution and in the solid-state: HgCl2 complexes with cyclen-based cryptands |
Authors: | Sah, Ajay Kumar |
Keywords: | Chemistry Hydrogen bonds HgCl2 complexes |
Issue Date: | 2017 |
Publisher: | RSC |
Abstract: | Structural evidence is reported for C–H⋯Cl− hydrogen bonds in solution and in the solid state of HgCl2 complexes with cyclen-based cryptands. These cyclen-based cryptands (1) and (2) are bridged by di- and triethylene glycol units, respectively, between two aromatic rings. The X-ray structure indicates that the 2/HgCl2 complex contains an acetonitrile molecule in the cavity. |
URI: | https://pubs.rsc.org/en/content/articlelanding/2017/dt/c6dt03390c http://dspace.bits-pilani.ac.in:8080/xmlui/handle/123456789/2777 |
Appears in Collections: | Department of Chemistry |
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