Selective Retention of Methanol over Ethanol by a Cyclen-Based Cryptand/Copper(II) Complex

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DC Field	Value	Language
dc.contributor.author	Sah, Ajay Kumar	-
dc.date.accessioned	2021-10-14T13:07:50Z	-
dc.date.available	2021-10-14T13:07:50Z	-
dc.date.issued	2013	-
dc.identifier.uri	https://pubs.acs.org/doi/10.1021/ic4021417	-
dc.identifier.uri	http://dspace.bits-pilani.ac.in:8080/xmlui/handle/123456789/2783	-
dc.description.abstract	A cyclen-based cryptand (2) was prepared in a two-step synthesis from dioxocyclen. When a Cu(CF3SO3)2 complex with 2 was prepared in methanol, the 2/Cu(CF3SO3)2 complex incorporated one methanol in the cavity formed by the diethyleneoxy unit and the NH group of the cyclen. When prepared in ethanol, the 2/Cu(CF3SO3)2 complex similarly incorporated one ethanol. Cold electrospray ionization mass spectrometry (CSI-MS) of the 2/Cu(CF3SO3)2/alcohol complexes selectively retains methanol over ethanol under CSI-MS conditions.	en_US
dc.language.iso	en	en_US
dc.publisher	ACS	en_US
dc.subject	Chemistry	en_US
dc.subject	Macrocyclic compounds	en_US
dc.subject	Ethers	en_US
dc.subject	Alcohols	en_US
dc.subject	Ethanol	en_US
dc.subject	Molecules	en_US
dc.title	Selective Retention of Methanol over Ethanol by a Cyclen-Based Cryptand/Copper(II) Complex	en_US
dc.type	Article	en_US
Appears in Collections:	Department of Chemistry

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