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Title: | Synthesis of cupric acetate selective receptor derived from alanyl glycoconjugate and their application in selective oxidation of benzylic alcohols |
Authors: | Sah, Ajay Kumar |
Keywords: | Chemistry Glucopyranosylamine Copper Fluorescence |
Issue Date: | Nov-2012 |
Publisher: | ACS |
Abstract: | Cupric acetate sensing ability of alanyl-(4,6-O-ethylidene-β-D-glucopyranosylamine) derived receptor (L-N2O2) has been explored using fluorescence and UV–visible absorption spectroscopy. Cupric acetate quenches the fluorescence intensity of L-N2O2 with a correlation coefficient, R = 0.978 and Stern Volmer constant, KSV = 38,067 M− 1 revealing the possibilities of interaction via dynamic mode. Further, copper complex of L-N2O2 has been utilized in selective oxidation of primary and secondary alcohols into the corresponding carbonyl compounds. |
URI: | https://www.sciencedirect.com/science/article/abs/pii/S1566736712003287?via%3Dihub http://dspace.bits-pilani.ac.in:8080/xmlui/handle/123456789/2785 |
Appears in Collections: | Department of Chemistry |
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