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http://dspace.bits-pilani.ac.in:8080/jspui/handle/123456789/2786| Title: | Saccharide derived dinuclear Cu(II) complex: An efficient catalyst for oxidation of catechol and benzylic alcohols |
| Authors: | Sah, Ajay Kumar Kumar, Anil |
| Keywords: | Chemistry Glucopyranosylamine Copper Catecholase TEMPO Ionic liquid |
| Issue Date: | Jan-2012 |
| Publisher: | Elsiever |
| Abstract: | Catalytical aspect of 4,6-O-ethylidene-β-D-glucopyranosylamine derived dinuclear Cu(II) complex has been explored. The complex exhibits good catecholase like activity and oxidizes model substrate 3,5-di-tert-butylcatechol to 3,5-di-tert-butyl-o-quinone. The complex also acts as selective catalyst to oxidize the primary and secondary alcohols to corresponding carbonyl compounds in excellent yield (65–82%) under mild conditions. |
| URI: | https://www.sciencedirect.com/science/article/abs/pii/S1566736711004080 http://dspace.bits-pilani.ac.in:8080/xmlui/handle/123456789/2786 |
| Appears in Collections: | Department of Chemistry |
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