Design, synthesis and evaluation of carbamoylmethylphosphine sulfide (CMPS)-based chelates for separation of lanthanides and actinides

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DC Field	Value	Language
dc.contributor.author	Sah, Ajay Kumar	-
dc.date.accessioned	2021-10-14T13:08:05Z	-
dc.date.available	2021-10-14T13:08:05Z	-
dc.date.issued	2007-11	-
dc.identifier.uri	https://www.sciencedirect.com/science/article/pii/S1631074807000495?via%3Dihub	-
dc.identifier.uri	http://dspace.bits-pilani.ac.in:8080/xmlui/handle/123456789/2787	-
dc.description.abstract	C3-symmetric triphenoxymethane platforms were substituted with carbamoylmethylphosphine sulfide arms and these tris-CMPS compounds were evaluated as extractants for f-element metal ions from 1 M nitric acid solution. Their properties were compared to the carbamoylmethylphosphine oxide derivatives on the same triphenoxymethane platform (tris-CMPO). The terbium complex of tris-CMPS was crystallized and examined via X-ray structural analysis to provide valuable insight into the binding properties of the soft tripodal chelate.	en_US
dc.language.iso	en	en_US
dc.publisher	Elsiever	en_US
dc.subject	Chemistry	en_US
dc.subject	Phosphine sulfide ligands	en_US
dc.subject	f-Element ions separation	en_US
dc.subject	Nuclear waste separation	en_US
dc.title	Design, synthesis and evaluation of carbamoylmethylphosphine sulfide (CMPS)-based chelates for separation of lanthanides and actinides	en_US
dc.type	Article	en_US
Appears in Collections:	Department of Chemistry

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