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DC Field | Value | Language |
---|---|---|
dc.contributor.author | Sah, Ajay Kumar | - |
dc.date.accessioned | 2021-10-14T13:09:05Z | - |
dc.date.available | 2021-10-14T13:09:05Z | - |
dc.date.issued | 2000 | - |
dc.identifier.uri | https://pubs.rsc.org/en/content/articlelanding/2000/DT/b004854m | - |
dc.identifier.uri | http://dspace.bits-pilani.ac.in:8080/xmlui/handle/123456789/2801 | - |
dc.description.abstract | A saccharide based ligand suitable for metal binding (HLCOOH) has been synthesized using 4,6-O-ethylidene-α-D-glucopyranose (4,6-O-EGP) and anthranilic acid. A few analogous glycosylamines with chloro and fluoro ortho substitutions have also been synthesized and characterised. Complexes of HLCOOH with Na+, K+, Mg2+, Ca2+, Ba2+, Cd2+ and Hg2+ have been isolated and characterised fully. The crystal structures of 4,6-O-EGP, the chloro analogue of HLCOOH and the K+ complex of LCOOH are established. The anomeric nature, orientation of the binding core and the co-ordination aspects of K+ have been derived from these structures. | en_US |
dc.language.iso | en | en_US |
dc.publisher | RSC | en_US |
dc.subject | Chemistry | en_US |
dc.subject | N-Glycosylamines of 4 | en_US |
dc.subject | 6-O-ethylidene-α-D-glucopyranose | en_US |
dc.title | N-Glycosylamines of 4,6-O-ethylidene-α-D-glucopyranose: synthesis, characterisation and structure of CO2H, Cl and F ortho-substituted phenyl derivatives and metal ion complexes of the CO2H derivative | en_US |
dc.type | Article | en_US |
Appears in Collections: | Department of Chemistry |
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