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Title: | Switchable regioselective hydroalkylation of 2-arylindoles with maleimides |
Authors: | Kumar, Anil |
Keywords: | Chemistry Hydroalkylation Maleimides |
Issue Date: | 2021 |
Publisher: | RSC |
Abstract: | A condition-based switchable regioselective hydroalkylation of 2-arylindoles with maleimides has been developed. The reaction in the presence of a Ru(II)-catalyst resulted in hydroalkylation at the ortho-position of the C2-aryl ring via C–H activation whereas the reaction in the absence of the catalyst in TFE resulted in C3-hydroalkylation. Various functional groups both on the indole ring and on the 2-phenyl ring were tolerated and a wide range of hydroalkylated products were obtained in moderate to high (37–88%) yields. |
URI: | https://pubs.rsc.org/en/content/articlelanding/2021/ob/d1ob00690h http://dspace.bits-pilani.ac.in:8080/xmlui/handle/123456789/2805 |
Appears in Collections: | Department of Chemistry |
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