Metal-free benzoylation of imidazoheterocycles by oxidative decarboxylation of arylglyoxylic acids

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DC Field	Value	Language
dc.contributor.author	Kumar, Anil	-
dc.date.accessioned	2021-10-14T13:09:52Z	-
dc.date.available	2021-10-14T13:09:52Z	-
dc.date.issued	2020	-
dc.identifier.uri	https://pubs.rsc.org/en/content/articlelanding/2020/ob/d0ob01842b	-
dc.identifier.uri	http://dspace.bits-pilani.ac.in:8080/xmlui/handle/123456789/2811	-
dc.description.abstract	A simple and straightforward approach has been realized for the direct benzoylation of imidazoheterocycles by oxidative decarboxylation of arylglyoxylic acids in the presence of K2S2O8 as an oxidant. Various functional groups were tolerated on both imidazoheterocycles and arylglyoxylic acids and a wide range of C5-benzoyl-imidazoheterocycles were obtained in good to high yields (50–84%). Radical trapping experiments confirmed the involvement of the radical pathway. The developed protocol is amenable for a scale-up reaction.	en_US
dc.language.iso	en	en_US
dc.publisher	RSC	en_US
dc.subject	Chemistry	en_US
dc.subject	Benzoylation	en_US
dc.subject	Imidazoheterocycles	en_US
dc.subject	Arylglyoxylic acids	en_US
dc.title	Metal-free benzoylation of imidazoheterocycles by oxidative decarboxylation of arylglyoxylic acids	en_US
dc.type	Article	en_US
Appears in Collections:	Department of Chemistry

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