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http://dspace.bits-pilani.ac.in:8080/jspui/handle/123456789/2836| Title: | Au-Catalyzed Synthesis of Thiopyrano[2,3-b]indoles Featuring Tandem Rearrangement and Hydroarylation |
| Authors: | Kumar, Anil Kumar, Dalip |
| Keywords: | Chemistry Indoles Sulfides Hydrocarbons |
| Issue Date: | 2017 |
| Publisher: | ACS |
| Abstract: | Gold(III)-catalyzed synthesis of 14-π electron heteroaromatic thiopyrano[2,3-b]indole is reported using conjugated enyne tethered indole sulfides, featuring skeletal rearrangement conjoined with intramolecular hydroarylation (via C3–H functionalization of the indole core) and oxidative aromatization. Subsequent Pd-catalyzed C–C coupling resulted in a 16-π electron heteroaromatic isothiochromeno[1,8,7-bcd]indole. |
| URI: | https://pubs.acs.org/doi/abs/10.1021/acs.orglett.7b00617 http://dspace.bits-pilani.ac.in:8080/xmlui/handle/123456789/2836 |
| Appears in Collections: | Department of Chemistry |
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