![DSpace logo](/jspui/image/logo.gif)
Please use this identifier to cite or link to this item:
http://dspace.bits-pilani.ac.in:8080/jspui/xmlui/handle/123456789/2845
Full metadata record
DC Field | Value | Language |
---|---|---|
dc.contributor.author | Kumar, Anil | - |
dc.date.accessioned | 2021-10-14T13:13:17Z | - |
dc.date.available | 2021-10-14T13:13:17Z | - |
dc.date.issued | 2016-06-07 | - |
dc.identifier.uri | https://onlinelibrary.wiley.com/doi/abs/10.1002/adsc.201600225 | - |
dc.identifier.uri | http://dspace.bits-pilani.ac.in:8080/xmlui/handle/123456789/2845 | - |
dc.description.abstract | An efficient protocol has been developed for the methylenation of imidazo[1,2-a]pyridines using dimethylacetamide (DMA) as methylene source in the presence of vanadyl acetylacetonate [VO(acac)2] as the catalyst and iodobenzene diacetate as the oxidant. The reaction involves coupling of sp3- and sp2-hybridized carbons and proceeds through the formation of an iminium ion. A wide variety of imidazo[1,2-a]pyridines were converted to bis(imidazo[1,2-a]pyridin-3-yl)methanes in good to excellent yields. A gram-scale reaction demonstrated the potential for the scale-up processes. | en_US |
dc.language.iso | en | en_US |
dc.publisher | Wiley | en_US |
dc.subject | Chemistry | en_US |
dc.subject | Vanadyl Acetylacetonate | en_US |
dc.subject | Catalyzed Methylenation | en_US |
dc.subject | Methylene | en_US |
dc.title | Vanadyl Acetylacetonate Catalyzed Methylenation of Imidazo[1,2-a]pyridines by Using Dimethylacetamide as a Methylene Source: Direct Access to Bis(imidazo[1,2-a]pyridin-3-yl)methanes | en_US |
dc.type | Article | en_US |
Appears in Collections: | Department of Chemistry |
Files in This Item:
There are no files associated with this item.
Items in DSpace are protected by copyright, with all rights reserved, unless otherwise indicated.