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Title: Indium triflate catalyzed microwave-assisted alkenylation of methoxyphenols: synthesis of indenes and chromenes
Authors: Kumar, Anil
Keywords: Chemistry
Indium triflate
Microwave-assisted
Methoxyphenols
Chromenes
Issue Date: 2015
Publisher: RSC
Abstract: In(OTf)3 catalyzed microwave-assisted alkenylation of methoxyphenols was investigated. Exclusive formation of either indenes or chromenes was observed depending on the position of the methoxy group on phenol. The structures of 1H-inden-4-ol derivatives (4a–e) and 4H-chromene derivatives (5a–j) were established by NMR (1H & 13C) and high-resolution mass spectra, which were further supported by single crystal X-ray analysis of 4c and 5a.
URI: https://pubs.rsc.org/en/content/articlelanding/2015/OB/C5OB01734C
http://dspace.bits-pilani.ac.in:8080/xmlui/handle/123456789/2854
Appears in Collections:Department of Chemistry

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