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Title: | Ionic Liquid-Supported Aldehyde: A Highly Efficient Scavenger for Primary Amines |
Authors: | Kumar, Anil |
Keywords: | Chemistry Salts Aldehydes Amines Chemical synthesis Solvents |
Issue Date: | 2012 |
Publisher: | ACS |
Abstract: | Novel aldehyde-functionalized ionic liquids have been synthesized and used as scavengers for primary amines in the synthesis of secondary amines. The yields of secondary amines are high (82–90%) with high purity. The advantages of the protocol over that with a polymer-supported aldehyde scavenger are the shorter reaction time, the homogeneous reaction medium, the high level of loading of the aldehyde group, easy monitoring of reaction, and characterization of intermediates. |
URI: | https://pubs.acs.org/doi/10.1021/co200151n http://dspace.bits-pilani.ac.in:8080/xmlui/handle/123456789/2924 |
Appears in Collections: | Department of Chemistry |
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