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Title: | Biomimetic Oxidation of Curcumin with Hydrogen Peroxide Catalyzed by 5,10,15,20-Tetraarylporphyrinatoiron(III) Chlorides in Dichloromethane |
Authors: | Kumar, Anil |
Keywords: | Chemistry Biomimetic oxidation Curcumin 5,10,15,20-tetraarylporphyrinatoiron(III) chloride |
Issue Date: | 2003 |
Publisher: | J-Stage |
Abstract: | The biomimetic oxidation of curcumin, a main turmeric pigment with hydrogen peroxide catalyzed by different 5,10,15,20-tetraarylporphyrinatoiron(III) chlorides [TAPFe(III)Cl] in dichloromethane has been studied to give a C–C coupled curcumin dimer in 40—70% yield. The structure of the dimer has been elucidated by 1H-, 13C-NMR, IR and FAB-Mass spectroscopic data. |
URI: | https://www.jstage.jst.go.jp/article/cpb/51/11/51_11_1345/_article http://dspace.bits-pilani.ac.in:8080/xmlui/handle/123456789/2968 |
Appears in Collections: | Department of Chemistry |
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