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Title: | l-Proline catalyzed direct diastereoselective aldol reactions: towards the synthesis of lyxo-(2S,3S,4S)-phytosphingosine |
Authors: | Kumar, Indresh |
Keywords: | Chemistry l-Proline Diastereoselective Phytosphingosine |
Issue Date: | 22-Aug-2007 |
Publisher: | Elsiever |
Abstract: | l-Proline catalyzed direct diastereoselective aldol reactions of α-amino aldehydes with cyclic ketones have been described and utilized further for the stereoselective synthesis of the 2-amino-1,3,4-triol unit as the phytosphingosines base backbone. This leads to the formal synthesis of (2S,3S,4S)-lyxo-phytosphingosine. |
URI: | https://www.sciencedirect.com/science/article/pii/S0957416607006052?via%3Dihub http://dspace.bits-pilani.ac.in:8080/xmlui/handle/123456789/2996 |
Appears in Collections: | Department of Chemistry |
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