Anchored Pd Complex in MCM-41 and MCM-48:  Novel Heterogeneous Catalysts for Hydrocarboxylation of Aryl Olefins and Alcohols

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DC Field	Value	Language
dc.contributor.author	Sarkar, Bibhas R.	-
dc.date.accessioned	2021-10-27T04:18:27Z	-
dc.date.available	2021-10-27T04:18:27Z	-
dc.date.issued	2002	-
dc.identifier.uri	https://pubs.acs.org/doi/10.1021/ja025991q	-
dc.identifier.uri	http://dspace.bits-pilani.ac.in:8080/xmlui/handle/123456789/3009	-
dc.description.abstract	We report here, for the first time, synthesis of anchored Pd complexes in mesoporous supports such as MCM-41 and MCM-48 as true heterogeneous catalysts for hydrocarboxylation of aryl olefins and alcohols to give excellent conversion (∼100%) and regioselectivity (∼99%) for 2-arylpropionic acids. The catalysts were characterized by powder-XRD, 31P CP-MAS NMR, FT-IR, TEM, XPS and ICP-AES. Recycle studies with these anchored Pd mesoporous catalysts were performed to confirm true heterogeneity.	en_US
dc.language.iso	en	en_US
dc.publisher	ACS	en_US
dc.subject	Chemistry	en_US
dc.subject	Palladium	en_US
dc.subject	Hydrocarbons	en_US
dc.subject	Alcohols	en_US
dc.subject	Catalysts	en_US
dc.subject	Selectivity	en_US
dc.title	Anchored Pd Complex in MCM-41 and MCM-48: Novel Heterogeneous Catalysts for Hydrocarboxylation of Aryl Olefins and Alcohols	en_US
dc.type	Article	en_US
Appears in Collections:	Department of Chemistry

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