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http://dspace.bits-pilani.ac.in:8080/jspui/handle/123456789/3009| Title: | Anchored Pd Complex in MCM-41 and MCM-48: Novel Heterogeneous Catalysts for Hydrocarboxylation of Aryl Olefins and Alcohols |
| Authors: | Sarkar, Bibhas R. |
| Keywords: | Chemistry Palladium Hydrocarbons Alcohols Catalysts Selectivity |
| Issue Date: | 2002 |
| Publisher: | ACS |
| Abstract: | We report here, for the first time, synthesis of anchored Pd complexes in mesoporous supports such as MCM-41 and MCM-48 as true heterogeneous catalysts for hydrocarboxylation of aryl olefins and alcohols to give excellent conversion (∼100%) and regioselectivity (∼99%) for 2-arylpropionic acids. The catalysts were characterized by powder-XRD, 31P CP-MAS NMR, FT-IR, TEM, XPS and ICP-AES. Recycle studies with these anchored Pd mesoporous catalysts were performed to confirm true heterogeneity. |
| URI: | https://pubs.acs.org/doi/10.1021/ja025991q http://dspace.bits-pilani.ac.in:8080/xmlui/handle/123456789/3009 |
| Appears in Collections: | Department of Chemistry |
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