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Title: | Revisiting Nucleophilic Substitution Reactions: Microwave-Assisted Synthesis of Azides, Thiocyanates, and Sulfones in an Aqueous Medium |
Authors: | Kumar, Dalip |
Keywords: | Chemistry Azides Chemical synthesis Substitution reactions |
Issue Date: | 28-Jul-2006 |
Publisher: | ACS |
Abstract: | A practical, rapid, and efficient microwave (MW) promoted synthesis of various azides, thiocyanates, and sulfones is described in an aqueous medium. This general and expeditious MW-enhanced nucleophilic substitution approach uses easily accessible starting materials such as halides or tosylates in reaction with alkali azides, thiocyanates, or sulfinates in the absence of any phase-transfer catalyst, and a variety of reactive functional groups are tolerated. |
URI: | https://pubs.acs.org/doi/abs/10.1021/jo061114h http://dspace.bits-pilani.ac.in:8080/xmlui/handle/123456789/3074 |
Appears in Collections: | Department of Chemistry |
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