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Title: | The reaction between hydrazines and β-dicarbonyl compounds: proposal for a mechanism |
Authors: | Kumar, Dalip |
Keywords: | Chemistry Hydrazines β-dicarbonyl compounds |
Issue Date: | Aug-2000 |
Publisher: | CSP |
Abstract: | The reaction between aryl or heteroarylhydrazines with fluorinated β-diketones (CF3COCH2COR) yields a variety of 3-, 5-, and 3,5-trifluoromethylpyrazoles and 5-trifluoromethyl-5-hydroxy-Δ2-pyrazolines. Twenty-one of such compounds have been isolated and identified by 13C and 19F NMR. Together with the results from the literature they provide a comprehensive overview of the reaction. Semi-empirical calculations at the PM3 level have been used to rationalize these results. The outcome that emerges seems to be that the dehydration of a pair of 3,5-dihydroxypyrazolidines kinetically controls the isomer formed.Key words: hydrazines, 1,3-diketones, pyrazolines, pyrazoles, PM3 calculations. |
URI: | https://cdnsciencepub.com/doi/abs/10.1139/v00-104?journalCode=cjc http://dspace.bits-pilani.ac.in:8080/xmlui/handle/123456789/3093 |
Appears in Collections: | Department of Chemistry |
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